Xara Designer Pro
Xara Designer Pro is a state-of-the-art photo editing software, that can edit at a professional level. This design makes it great for professionals but is less accessable for people who are unfamiliar with photo editing or web desgin.
Another notable feature of Xara Designer Pro is its Graphic Design feature, which lets it excel at web design. It gives you the ability to create Flash Animations (GIFs) and Web Bitmap photos (BMP,PNG,JPG)
If you’re interested in trying out this program, feel free to download the trial here: http://www.xara.com/us/downloads/designer/